Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-substituted ortho-perylenes displaying four reversible oxidations or reductions

Via regioselective Ir-catalyzed C–H borylation and subsequent reactions (i.e., viaBr(4)-Per or (BF(3)K)(4)-Per intermediates), we have introduced strong π-donors and acceptors at the 2,5,8,11-positions of perylene leading to unusual properties. Thus, incorporation of four donor diphenylamine (DPA) o...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Merz, Julia, Steffen, Andreas, Nitsch, Jörn, Fink, Julian, Schürger, Claudia B., Friedrich, Alexandra, Krummenacher, Ivo, Braunschweig, Holger, Moos, Michael, Mims, David, Lambert, Christoph, Marder, Todd B.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6761871/
https://ncbi.nlm.nih.gov/pubmed/31588303
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02420d
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