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Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides

Although the chemistry of uranium-ligand multiple bonding is burgeoning, analogous complexes involving other actinides such as thorium remain rare and there are not yet any terminal thorium nitrides outside of cryogenic matrix isolation conditions. Here, we report evidence that reduction of a thoriu...

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Detalles Bibliográficos
Publicado en:Nat Commun
Main Authors: Du, Jingzhen, Alvarez-Lamsfus, Carlos, Wildman, Elizabeth P., Wooles, Ashley J., Maron, Laurent, Liddle, Stephen T.
Formato: Artigo
Idioma:Inglês
Publicado: Nature Publishing Group UK 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6744569/
https://ncbi.nlm.nih.gov/pubmed/31519900
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-12206-5
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