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Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides

Although the chemistry of uranium-ligand multiple bonding is burgeoning, analogous complexes involving other actinides such as thorium remain rare and there are not yet any terminal thorium nitrides outside of cryogenic matrix isolation conditions. Here, we report evidence that reduction of a thoriu...

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Bibliografiske detaljer
Udgivet i:Nat Commun
Main Authors: Du, Jingzhen, Alvarez-Lamsfus, Carlos, Wildman, Elizabeth P., Wooles, Ashley J., Maron, Laurent, Liddle, Stephen T.
Format: Artigo
Sprog:Inglês
Udgivet: Nature Publishing Group UK 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6744569/
https://ncbi.nlm.nih.gov/pubmed/31519900
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-12206-5
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