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Reaction between Peroxy and Alkoxy Radicals Can Form Stable Adducts

[Image: see text] Peroxy (RO(2)) and alkoxy (RO) radicals are prototypical intermediates in any hydrocarbon oxidation. In this work, we use computational methods to (1) study the mechanism and kinetics of the RO(2) + OH reaction for previously unexplored “R” structures (R = CH(O)CH(2) and R = CH(3)C...

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Pubblicato in:J Phys Chem Lett
Autori principali: Iyer, Siddharth, Rissanen, Matti P., Kurtén, Theo
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2019
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6727596/
https://ncbi.nlm.nih.gov/pubmed/30958011
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.9b00405
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