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Radical reactivity in the condensed phase: Intermolecular versus intramolecular reactions of alkoxy radicals

Condensed-phase alkoxy (RO) radicals can undergo unimolecular (e.g., intramolecular H-atom abstraction) reactions as well as bimolecular (intermolecular H-atom abstraction) reactions, though the competition between these two channels is not well constrained. Here we examine this branching, by genera...

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Detalhes bibliográficos
Publicado no:J Phys Chem Lett
Main Authors: Carrasquillo, Anthony J., Daumit, Kelly E., Kroll, Jesse H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5348301/
https://ncbi.nlm.nih.gov/pubmed/26266621
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.5b00913
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