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The reaction of methyl peroxy and hydroxyl radicals as a major source of atmospheric methanol

Methyl peroxy, a key radical in tropospheric chemistry, was recently shown to react with the hydroxyl radical at an unexpectedly high rate. Here, the molecular reaction mechanisms are elucidated using high-level quantum chemical methodologies and statistical rate theory. Formation of activated methy...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Nat Commun
Hauptverfasser: Müller, Jean-François, Liu, Zhen, Nguyen, Vinh Son, Stavrakou, Trissevgeni, Harvey, Jeremy N., Peeters, Jozef
Format: Artigo
Sprache:Inglês
Veröffentlicht: Nature Publishing Group 2016
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5071643/
https://ncbi.nlm.nih.gov/pubmed/27748363
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms13213
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