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Attempted synthesis of a meta-metalated calix[4]arene

An evidence for the formation of a rare meta-metalated inherently chiral calix[4]arene is described. Our strategy involved using a mesoionic carbene to direct C–H activation, but proved to form an unexpectedly unstable intermediate that was identified through high-resolution mass spectrometry. On ro...

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Detalles Bibliográficos
Publicado en:Beilstein J Org Chem
Autores principales: Jurisch, Christopher D, Arnott, Gareth E
Formato: Artigo
Lenguaje:Inglês
Publicado: Beilstein-Institut 2019
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6719732/
https://ncbi.nlm.nih.gov/pubmed/31501666
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.195
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