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Attempted synthesis of a meta-metalated calix[4]arene
An evidence for the formation of a rare meta-metalated inherently chiral calix[4]arene is described. Our strategy involved using a mesoionic carbene to direct C–H activation, but proved to form an unexpectedly unstable intermediate that was identified through high-resolution mass spectrometry. On ro...
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| Udgivet i: | Beilstein J Org Chem |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Beilstein-Institut
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6719732/ https://ncbi.nlm.nih.gov/pubmed/31501666 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.195 |
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