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Total Synthesis of (–)-Salinosporamide A via a Late Stage C-H Insertion
The synthesis of (–)-salinosporamide A, a proteasome inhibitor, is described. The synthesis highlights the assembly of a densely decorated pyrrolidinone core via an aza-Payne/hydroamination sequence. Central to the success of the synthesis is a late stage C–H insertion reaction to functionalize a st...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6715302/ https://ncbi.nlm.nih.gov/pubmed/30887693 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900340 |
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