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Mononuclear, Nonheme, High-Spin {FeNO}(7/8) Complexes Supported by a Sterically Encumbered N(4)S-Thioether Ligand
The synthesis of a new nonheme iron NO binding complex, [Fe(II)(CH(3)CN)(N3Py(2Ph)SEtCN)](BF(4))(2) (1), is reported. Complex 1, which contains two sterically encumbering phenyl substituents, exhibits a hs Fe(II) (S = 2) ground state in contrast to the S = 0 ground state for unsubstituted [Fe(II)(CH...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6715289/ https://ncbi.nlm.nih.gov/pubmed/31328501 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b01475 |
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