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Inherent atomic mobility changes in carbocation intermediates during the sesterterpene cyclization cascade
We previously showed that the regio- and stereoselectivity in terpene-forming reactions are determined by the conformations of the carbocation intermediates, which reflect the initial conformation of the substrate, geranylfarnesyl diphosphate (GFPP). However, it remains unclear how the initial confo...
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| Pubblicato in: | Beilstein J Org Chem |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Beilstein-Institut
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6693403/ https://ncbi.nlm.nih.gov/pubmed/31467610 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.184 |
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