“Cation-Stitching Cascade”: exquisite control of terpene cyclization in cyclooctatin biosynthesis

Terpene cyclization is orchestrated by terpene cyclases, which are involved in the biosynthesis of various cyclic natural products, but understanding the origin and mechanism of the selectivity of terpene cyclization is challenging. In this work, we describe an in-depth mechanistic study on cyclooct...

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Publicat a:Sci Rep
Autors principals: Sato, Hajime, Teramoto, Kazuya, Masumoto, Yui, Tezuka, Noriyuki, Sakai, Kenta, Ueda, Shota, Totsuka, Yusuke, Shinada, Tetsuro, Nishiyama, Makoto, Wang, Chao, Kuzuyama, Tomohisa, Uchiyama, Masanobu
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group 2015
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4683443/
https://ncbi.nlm.nih.gov/pubmed/26681256
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep18471
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