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Solventless and Metal-free Regioselective Hydrofluorination of Functionalized Alkynes and Allenes: An Efficient Protocol for the Synthesis of gem-Difluorides
The combination of two easily handled, highly acidic liquid HF complex reagents, DMPU-12HF and KHSO(4)-13HF, generated a highly acidic fluorination system that facilitated exclusive Markovnikov addition of HF to widely functionalized alkynes, including alkyne tethered drugs, or allenes to produce ge...
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| 出版年: | Green Chem |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6688647/ https://ncbi.nlm.nih.gov/pubmed/31404296 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8gc03876g |
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