Substituent-controlled, mild oxidative fluorination of iodoarenes: synthesis and structural study of aryl I(iii)- and I(v)-fluorides

We report a mild approach to the synthesis of difluoro(aryl)-λ(3)-iodanes (aryl-IF(2) compounds) and tetrafluoro(aryl)-λ(5)-iodanes (aryl-IF(4) compounds) using trichloroisocyanuric acid (TCICA) and potassium fluoride (KF). Under these reaction conditions, selective access to either the I(iii)- or I...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Häfliger, Joel, Pitts, Cody Ross, Bornemann, Dustin, Käser, Roland, Santschi, Nico, Charpentier, Julie, Otth, Elisabeth, Trapp, Nils, Verel, René, Lüthi, Hans Peter, Togni, Antonio
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6685355/
https://ncbi.nlm.nih.gov/pubmed/31588294
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02162k
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