Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic–Phosphinic Mixed Anhydride from CO(2)

Direct synthesis of carboxylic–phosphinic mixed anhydrides has been achieved by treating carbon dioxide with N‐phosphine oxide‐substituted imidazolylidenes (PoxIms) that contain both nucleophilic carbene and electrophilic phosphorus moieties. This novel mixed anhydride was efficiently derivatized in...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Hoshimoto, Yoichi, Asada, Takahiro, Hazra, Sunit, Kinoshita, Takuya, Sombut, Panukorn, Kumar, Ravindra, Ohashi, Masato, Ogoshi, Sensuke
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2016
Témata:
Communications
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6680262/
https://ncbi.nlm.nih.gov/pubmed/27891755
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201609710
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