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Two-step synthesis of chiral fused tricyclic scaffolds from phenols via desymmetrization on nickel

Tricyclic furan derivatives with multiple chiral centers are ubiquitous in natural products. Construction of such tricyclic scaffolds in a stereocontrolled, step-economic, and atom-economic manner is a key challenge. Here we show a nickel-catalyzed highly enantioselective synthesis of hydronaphtho[1...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Kumar, Ravindra, Hoshimoto, Yoichi, Tamai, Eri, Ohashi, Masato, Ogoshi, Sensuke
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5484674/
https://ncbi.nlm.nih.gov/pubmed/28652575
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-017-00068-8
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