Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic–Phosphinic Mixed Anhydride from CO(2)

Direct synthesis of carboxylic–phosphinic mixed anhydrides has been achieved by treating carbon dioxide with N‐phosphine oxide‐substituted imidazolylidenes (PoxIms) that contain both nucleophilic carbene and electrophilic phosphorus moieties. This novel mixed anhydride was efficiently derivatized in...

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Veröffentlicht in:Angew Chem Int Ed Engl
Hauptverfasser: Hoshimoto, Yoichi, Asada, Takahiro, Hazra, Sunit, Kinoshita, Takuya, Sombut, Panukorn, Kumar, Ravindra, Ohashi, Masato, Ogoshi, Sensuke
Format: Artigo
Sprache:Inglês
Veröffentlicht: John Wiley and Sons Inc. 2016
Schlagworte:
Communications
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6680262/
https://ncbi.nlm.nih.gov/pubmed/27891755
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201609710
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