Isothiourea‐Catalysed Acylative Kinetic Resolution of Aryl–Alkenyl (sp(2) vs. sp(2)) Substituted Secondary Alcohols

The non‐enzymatic acylative kinetic resolution of challenging aryl–alkenyl (sp(2) vs. sp(2)) substituted secondary alcohols is described, with effective enantiodiscrimination achieved using the isothiourea organocatalyst HyperBTM (1 mol %) and isobutyric anhydride. The kinetic resolution of a wide r...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Musolino, Stefania F., Ojo, O. Stephen, Westwood, Nicholas J., Taylor, James E., Smith, Andrew D.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6680239/
https://ncbi.nlm.nih.gov/pubmed/27775200
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201604788
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