Isothiourea-catalysed enantioselective pyrrolizine synthesis: synthetic and computational studies

The catalytic enantioselective synthesis of a range of cis-pyrrolizine carboxylate derivatives with outstanding stereocontrol (14 examples, >95 : 5 dr, >98 : 2 er) through an isothiourea-catalyzed intramolecular Michael addition-lactonisation and ring-opening approach from the corresponding en...

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Detalhes bibliográficos
Publicado no:Org Biomol Chem
Main Authors: Stark, Daniel G., Williamson, Patrick, Gayner, Emma R., Musolino, Stefania F., Kerr, Ryan W. F., Taylor, James E., Slawin, Alexandra M. Z., O'Riordan, Timothy J. C., Macgregor, Stuart A., Smith, Andrew D.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5314687/
https://ncbi.nlm.nih.gov/pubmed/27489030
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6ob01557c
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