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Ligand-Controlled Regiodivergent Enantioselective Rhodium-Catalyzed Alkene Hydroboration
Regiocontrol in the rhodium-catalyzed boration of vinyl arenes is typically dominated by the presence of the conjugated aryl substituent. However, small differences in TADDOL-derived chiral monophosphite ligands can override this effect and direct rhodium-catalyzed hydroboration of β-aryl and -heter...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
|---|---|
| Hoofdauteurs: | , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2019
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6663592/ https://ncbi.nlm.nih.gov/pubmed/31067341 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903308 |
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