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Catalytic Alkyne Arylation Using Traceless Directing Groups
Using Pd(0)/Mandyphos, we achieve a three-component aminoarylation of alkynes to generate enamines, which hydrolyze to either α-arylphenones or α,α-diarylketones. This Pd-catalyzed method overcomes established pathways to enable the use of amines as traceless directing groups for C–C bond formation....
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6661160/ https://ncbi.nlm.nih.gov/pubmed/30066448 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201804955 |
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