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meta-C–H arylation of fluoroarenes via traceless directing group relay strategy

While several methods for the ortho selective arylation of fluoroarenes, meta-functionalisation has never been achieved. We report a new methodology, based on the traceless directing group relay concept, leading to the first meta-selective (hetero)arylation of fluoroarenes. In this strategy, CO(2) i...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Font, Marc, Spencer, Andrew R. A., Larrosa, Igor
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6137440/
https://ncbi.nlm.nih.gov/pubmed/30310635
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02417k
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