Učitavanje...
meta-Selective C–H Arylation of Fluoroarenes and Simple Arenes
Fluorine is known to promote ortho- C–H metalation.(1) Based upon this reactivity, we employed an activated norbornene to trap the ortho-palladation intermediate and relay to the meta-position, leading to a meta-selective C–H arylation of fluoroarenes. Deuterium experiment suggests that this meta-ar...
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| Izdano u: | Angew Chem Int Ed Engl |
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| Glavni autori: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2020
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7485903/ https://ncbi.nlm.nih.gov/pubmed/32333462 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002865 |
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