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Regiodivergent Photocyclization of Dearomatized Acylphloroglu-cinols: Asymmetric Syntheses of (−)-Nemorosone and (−)-6-epi-Garcimultiflorone A
Regiodivergent photocyclization of dearomatized acylphloroglucinol substrates has been developed to produce type A polycyclic polyprenylated acylphloroglucinol (PPAP) derivatives using an excited-state intramolecular proton transfer (ESIPT) process. Using this strategy, we achieved the enantioselect...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2019
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6659400/ https://ncbi.nlm.nih.gov/pubmed/31264859 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b05600 |
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