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Asymmetric Dearomatization/Cyclization Enables Access to Polycyclic Chemotypes
Enantioenriched, polycyclic compounds were obtained from a simple acylphloroglucinol scaffold. Highly enantioselective dearomatization was accomplished using a Trost ligand-palladium(0) complex. A computational DFT model was developed to rationalize observed enantioselectivities and revealed a key r...
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| Pubblicato in: | European J Org Chem |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5222469/ https://ncbi.nlm.nih.gov/pubmed/28082832 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201601003 |
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