Hyperpolarizing Concentrated Metronidazole (15)NO(2) Group Over Six Chemical Bonds with More Than 15% Polarization and 20 Minute Lifetime

NMR hyperpolarization of uniformly (15)N-labeled metronidazole-(15)N(3) is demonstrated using SABRE-SHEATH (Signal Amplification by Reversible Exchange in SHield Enables Alignment Transfer to Heteronuclei). In this antibiotic, a (15)NO(2) group is hyperpolarized via spin relays created by (15)N spin...

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Detaylı Bibliyografya
Yayımlandı:Chemistry
Asıl Yazarlar: Shchepin, Roman V., Birchall, Jonathan R., Chukanov, Nikita V., Kovtunov, Kirill V., Koptyug, Igor V., Theis, Thomas, Warren, Warren S., Gelovani, Juri G., Goodson, Boyd M., Shokouhi, Sepideh, Rosen, Matthew S., Yen, Yi-Fen, Pham, Wellington, Chekmenev, Eduard Y.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2019
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Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6658333/
https://ncbi.nlm.nih.gov/pubmed/30964568
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201901192
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