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Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes

Owing to the pervasiveness of hydroxyl groups in natural isolates, alcohol derivatives are alluring directing groups. Herein, an alcohol-derived sulfamate ester guides the light initiated xanthylation of primary, secondary, or tertiary centers. This process enables formal directed deuteration, azida...

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Publicado en:J Org Chem
Main Authors: Ayer, Suraj K., Roizen, J. L.
Formato: Artigo
Idioma:Inglês
Publicado: 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6656367/
https://ncbi.nlm.nih.gov/pubmed/30779561
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b00105
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