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Synthesis of 6,12-Disubstituted Methanodibenzo[b,f][1,5]dioxocins: Pyrrolidine Catalyzed Self-Condensation of 2′-Hydroxyacetophenones

The preparation of unprecedented 6,12-disubstituted methanodibenzo[b,f][1,5]dioxocins from pyrrolidine catalyzed self-condensation of 2′-hydroxyacetophenones is herein described. This method provides easy access to this highly bridged complex core, resulting in construction of two C–O and two C–C bo...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Assoah, Benedicta, Riihonen, Vesa, Vale, João R., Valkonen, Arto, Candeias, Nuno R.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6651863/
https://ncbi.nlm.nih.gov/pubmed/31261870
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24132405
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