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A remarkably strained cyclopyrenylene trimer that undergoes metal-free direct oxygen insertion into the biaryl C–C σ-bond
A remarkably strained cyclopyrenylene trimer CP3 was synthesized and it underwent the first biaryl C–C σ-bond cleavage by direct oxygen insertion without the aid of any metal agents. A priori highly strained CP3 exhibits the longest wavelength emission among all pyrene-based fluorophores due to the...
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| Опубликовано в: : | Chem Sci |
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| Главные авторы: | , , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
Royal Society of Chemistry
2019
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6640197/ https://ncbi.nlm.nih.gov/pubmed/31391899 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01777a |
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