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A remarkably strained cyclopyrenylene trimer that undergoes metal-free direct oxygen insertion into the biaryl C–C σ-bond

A remarkably strained cyclopyrenylene trimer CP3 was synthesized and it underwent the first biaryl C–C σ-bond cleavage by direct oxygen insertion without the aid of any metal agents. A priori highly strained CP3 exhibits the longest wavelength emission among all pyrene-based fluorophores due to the...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Kurosaki, Ryo, Hayashi, Hironobu, Suzuki, Mitsuharu, Jiang, Julong, Hatanaka, Miho, Aratani, Naoki, Yamada, Hiroko
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6640197/
https://ncbi.nlm.nih.gov/pubmed/31391899
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01777a
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