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Thiopeptide Pyridine Synthase TbtD Catalyzes an Intermolecular Formal Aza-Diels-Alder Reaction
Thiopeptide pyridine synthases catalyze a multistep reaction involving a unique and non-spontaneous intramolecular aza-[4+2] cycloaddition between two dehydroalanines to forge a tri-substituted pyridine core. We discovered that the in vitro activity of pyridine synthases from the thiocillin and thio...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6637763/ https://ncbi.nlm.nih.gov/pubmed/30653303 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11852 |
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