Improved synthesis of icosahedral carboranes containing exopolyhedral B–C and C–C bonds

Carboranes are boron-rich molecular clusters possessing electronic characteristics that allow for orthogonal approaches to vertex-selective modifications. We report improved functionalization methods utilizing orthogonal chemistry to achieve efficient substitution at electron-rich B-vertices and ele...

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Pubblicato in:Tetrahedron
Autori principali: Anderson, Kierstyn P., Mills, Harrison A., Mao, Chantel, Kirlikovali, Kent O., Axtell, Jonathan C., Rheingold, Arnold L., Spokoyny, Alexander M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6625786/
https://ncbi.nlm.nih.gov/pubmed/31303685
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2018.11.040
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