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Oxidative Generation of Boron-Centered Radicals in Carboranes
We report the first indirect observation and use of boron vertex-centered carboranyl radicals generated by the oxidation of modified carboranyl precursors. These radical intermediates are formed by the direct oxidation of a B─B bond between a boron cluster cage and an exopolyhedral boron-based subst...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7276281/ https://ncbi.nlm.nih.gov/pubmed/32073842 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c00300 |
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