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Synthesis of 9-Borafluorene Analogues Featuring a Three-Dimensional 1,1’-Bis(o-carborane) Backbone

The synthesis of [1,1’-bis(o-carboranyl)]boranes was achieved through the deprotonation of 1,1’-bis(o-carborane) reagents followed by salt metathesis with ((i)Pr)(2)NBCl(2). X-ray crystallography confirms planar central BC(4) rings and Gutmann-Beckett studies reveal an increase in Lewis acidity at t...

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Détails bibliographiques
Publié dans:Chem Commun (Camb)
Auteurs principaux: Yruegas, Sam, Axtell, Jonathan C., Kirlikovali, Kent O., Spokoyny, Alexander M., Martin, Caleb D.
Format: Artigo
Langue:Inglês
Publié: 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6624192/
https://ncbi.nlm.nih.gov/pubmed/30706915
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc10087j
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