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Synthesis of 9-Borafluorene Analogues Featuring a Three-Dimensional 1,1’-Bis(o-carborane) Backbone
The synthesis of [1,1’-bis(o-carboranyl)]boranes was achieved through the deprotonation of 1,1’-bis(o-carborane) reagents followed by salt metathesis with ((i)Pr)(2)NBCl(2). X-ray crystallography confirms planar central BC(4) rings and Gutmann-Beckett studies reveal an increase in Lewis acidity at t...
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| 發表在: | Chem Commun (Camb) |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6624192/ https://ncbi.nlm.nih.gov/pubmed/30706915 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc10087j |
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