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Deuterium Isotope Effects in α - β Pyranose and in Pyranose-Furanose Interconversions

Rates of mutarotation, catalytic coefficients, and isotope effects are reported for the mutarotations of α-d-xylose, α-d-glucose, and β-d-fructose in H(2)O and in D(2)O at 20 °C. The isotope effects (k(H)/k(D)) for the mutarotation of β-d-fructose (a pyranose-furanose interconversion) parallel in st...

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Pubblicato in:J Res Natl Bur Stand A Phys Chem
Autori principali: Isbell, Horace S., Wade, Clarence W. R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Institute of Standards and Technology 1967
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6624696/
https://ncbi.nlm.nih.gov/pubmed/31824039
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.071A.020
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