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β‐Deuterium Isotope Effects on Firefly Luciferase Bioluminescence
A 5,5‐d(2)‐luciferin was prepared to measure isotope effects on reactions of two intermediates in firefly bioluminescence: emission by oxyluciferin and elimination of a putative luciferyl adenylate hydroperoxide to dehydroluciferin. A negligible isotope effect on bioluminescence provides further sup...
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| Pubblicato in: | ChemistryOpen |
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| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5715289/ https://ncbi.nlm.nih.gov/pubmed/29226056 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201700136 |
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