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Use of (15)N NMR spectroscopy to probe covalency in a thorium nitride
Reaction of the thorium metallacycle, [Th{N(R)(SiMe(2))CH(2)}(NR(2))(2)] (R = SiMe(3)) with 1 equiv. of NaNH(2) in THF, in the presence of 18-crown-6, results in formation of the bridged thorium nitride complex, [Na(18-crown-6)(Et(2)O)][(R(2)N)(3)Th(μ-N)(Th(NR(2))(3)] ([Na][1]), which can be isolate...
Guardat en:
| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6615217/ https://ncbi.nlm.nih.gov/pubmed/31367305 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01960j |
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