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Branched-Selective Direct α-Alkylation of Cyclic Ketones with Simple Alkenes
Herein, we describe an intermolecular direct branched-selective α-alkylation of cyclic ketones with simple alkenes as the alkylation agents. Through an enamine-transition metal cooperative catalysis mode, the α-alkylation is realized in an atom- and step-economic manner with excellent branched selec...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6604859/ https://ncbi.nlm.nih.gov/pubmed/30707491 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900301 |
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