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Enantioselective N–alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction

The development of an intermolecular and enantioselective aza-Wacker reaction is described. Using indoles as the N-source, a selection of alkenols as the coupling partner enables selective β-hydride elimination towards the alcohol. This strategy preserves the newly formed stereocenter by preventing...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Allen, Jamie R., Bahamonde, Ana, Furukawa, Yukino, Sigman, Matthew S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6583780/
https://ncbi.nlm.nih.gov/pubmed/31117643
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b01476
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