A Nonheme Sulfur-ligated {FeNO}(6) Complex and Comparison with Redox-Interconvertible {FeNO}(7) and {FeNO}(8) Analogs

A nonheme {FeNO}(6) complex, [Fe(NO)(N3PyS)](2+), was synthesized by reversible, one-electron oxidation of an {FeNO}(7) analog. This complex completes the first known series of sulfur-ligated {FeNO}(6−8) complexes. All three {FeNO}(6−8) complexes are readily interconverted by one-electron oxidation/...

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Udgivet i:Angew Chem Int Ed Engl
Main Authors: Dey, Aniruddha, Confer, Alex M., Vilbert, Avery C., Moënne-Loccoz, Pierre, Lancaster, Kyle M., Goldberg, David P.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6576265/
https://ncbi.nlm.nih.gov/pubmed/30125450
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201806146
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