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Experimental and Computational Study of the (Z)‑Selective Formation of Trisubstituted Olefins and Benzo-Fused Oxacycles from the Ruthenium-Catalyzed Dehydrative C–H Coupling of Phenols with Ketones

The cationic Ru–H complex was found to be an effective catalyst for the dehydrative C–H coupling of phenols with ketones to form the trisubstituted olefin products. The coupling of phenol with linear ketones led to highly stereoselective formation of the (Z)-olefin products. The dehydrative coupling...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Lee, Hanbin, Mane, Manoj V., Ryu, Ho, Sahu, Debashis, Baik, Mu-Hyun, Yi, Chae S.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6558961/
https://ncbi.nlm.nih.gov/pubmed/30032611
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05875
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