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A Relay Strategy Actuates Pre-Existing Trisubstituted Olefins in Monoterpenoids for Cross-Metathesis with Trisubstituted Alkenes

[Image: see text] A retrosynthetic disconnection–reconnection analysis of epoxypolyenes—substrates that can undergo cyclization to podocarpane-type tricycles—reveals relay-actuated Δ(6,7)-functionalized monoterpenoid alcohols for ruthenium benzylidene catalyzed olefin cross-metathesis with homopreny...

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Bibliografske podrobnosti
izdano v:J Org Chem
Main Authors: Bahou, Karim A., Braddock, D. Christopher, Meyer, Adam G., Savage, G. Paul, Shi, Zhensheng, He, Tianyou
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2020
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7145354/
https://ncbi.nlm.nih.gov/pubmed/32191466
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00067
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