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Group 4 Metal and Lanthanide Complexes in the Oxidation State +3 with Tris(trimethylsilyl)silyl Ligands
[Image: see text] A number of paramagnetic silylated d(1) group 4 metallates were prepared by reaction of potassium tris(trimethylsilyl)silanide with group 4 metallates of the type K[Cp(2)MCl(2)] (M = Ti, Zr, Hf). The outcomes of the reactions differ for all three metals. While for the hafnium case...
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| Udgivet i: | Inorg Chem |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical Society
2019
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| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6534343/ https://ncbi.nlm.nih.gov/pubmed/31066552 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b00866 |
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