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Metalated Oligosilanylstibines

[Image: see text] The reaction of a cyclic disilylated bromostibine with magnesium yields a rare example of a magnesium stibide that can be silylated with trimethylchlorosilane. Reaction of the thus-obtained trisilylated stibine with potassium tert-butoxide gives a potassium stibide in a clean react...

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Détails bibliographiques
Publié dans:Organometallics
Auteurs principaux: Zitz, Rainer, Baumgartner, Judith, Marschner, Christoph
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2015
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4413693/
https://ncbi.nlm.nih.gov/pubmed/25937692
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om501297h
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