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Neutral “Cp-Free” Silyl-Lanthanide(II) Complexes: Synthesis, Structure, and Bonding Analysis

[Image: see text] Complexes featuring lanthanide silicon bonds represent a research area still in its infancy. Herein, we report a series of Cp-free lanthanide (+II) complexes bearing σ-bonded silyl ligands. By reactions of LnI(2) (Ln = Yb, Eu, Sm) either with a 1,4-oligosilanyl dianion [K-Si(SiMe(3...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Zitz, Rainer, Hlina, Johann, Gatterer, Karl, Marschner, Christoph, Szilvási, Tibor, Baumgartner, Judith
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2015
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4510641/
https://ncbi.nlm.nih.gov/pubmed/26132550
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b01072
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