Ligand-Enabled β-C(sp(3))–H Olefination of Free Carboxylic Acids

An acetyl-protected aminoethyl phenyl thioether has been developed to promote C(sp(3))–H activation. Significant ligand enhancement is demonstrated by the realization of the first Pd(II)-catalyzed olefination of C(sp(3))–H bonds of free carboxylic acids without using an auxiliary. Subsequent lactoni...

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Gepubliceerd in:J Am Chem Soc
Hoofdauteurs: Zhuang, Zhe, Yu, Chang-Bin, Chen, Gang, Wu, Qing-Feng, Hsiao, Yi, Joe, Candice L., Qiao, Jennifer X., Poss, Michael A., Yu, Jin-Quan
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2018
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Article
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6524951/
https://ncbi.nlm.nih.gov/pubmed/30029574
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b06527
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