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Ligand-Enabled β-C(sp(3))–H Olefination of Free Carboxylic Acids
An acetyl-protected aminoethyl phenyl thioether has been developed to promote C(sp(3))–H activation. Significant ligand enhancement is demonstrated by the realization of the first Pd(II)-catalyzed olefination of C(sp(3))–H bonds of free carboxylic acids without using an auxiliary. Subsequent lactoni...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2018
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6524951/ https://ncbi.nlm.nih.gov/pubmed/30029574 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b06527 |
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