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Ligand‐Enabled γ‐C(sp(3))−H Olefination of Free Carboxylic Acids
We report the ligand‐enabled C−H activation/olefination of free carboxylic acids in the γ‐position. Through an intramolecular Michael addition, δ‐lactones are obtained as products. Two distinct ligand classes are identified that enable the challenging palladium‐catalyzed activation of free carboxyli...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7496353/ https://ncbi.nlm.nih.gov/pubmed/32250014 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002362 |
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