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A Redox‐Active Nickel Complex that Acts as an Electron Mediator in Photochemical Giese Reactions
We report a simple protocol for the photochemical Giese addition of C(sp(3))‐centered radicals to a variety of electron‐poor olefins. The chemistry does not require external photoredox catalysts. Instead, it harnesses the excited‐state reactivity of 4‐alkyl‐1,4‐dihydropyridines (4‐alkyl‐DHPs) to gen...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6519288/ https://ncbi.nlm.nih.gov/pubmed/30747467 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201814497 |
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